Nitrosobenzene
- Product Name
- Nitrosobenzene
- CAS No.
- 586-96-9
- Chemical Name
- Nitrosobenzene
- Synonyms
- nob;Nitrosobenzol;NITROSOBENZENE;nitroso-benzen;benzene,nitroso-;p-nitrosobenzene;1-Nitrosobenzene;Nitrosobenzene>Nitrosobenzene,NOB;Nitrosobenzene >=97%
- CBNumber
- CB0394996
- Molecular Formula
- C6H5NO
- Formula Weight
- 107.11
- MOL File
- 586-96-9.mol
Nitrosobenzene Property
- Melting point:
- 65-69 °C (lit.)
- Boiling point:
- 59 °C/18 mmHg (lit.)
- Density
- 1.1697 (rough estimate)
- refractive index
- 1.5389 (estimate)
- storage temp.
- 2-8°C
- solubility
- Chloroform (Sparingly), Methanol (Slightly)
- form
- Solid
- color
- White to Brown
- BRN
- 605688
- Stability:
- Stable. Incompatible with strong oxidizing agents.
- InChIKey
- NLRKCXQQSUWLCH-UHFFFAOYSA-N
- CAS DataBase Reference
- 586-96-9
- NIST Chemistry Reference
- Benzene, nitroso-(586-96-9)
- EPA Substance Registry System
- Nitrosobenzene (586-96-9)
Safety
- Hazard Codes
- T
- Risk Statements
- 20/21-25
- Safety Statements
- 26-36/37-45
- RIDADR
- UN 2811 6.1/PG 3
- WGK Germany
- 3
- RTECS
- DA6497525
- F
- 9-23
- HazardClass
- 6.1(b)
- PackingGroup
- III
- HS Code
- 29042000
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H301Toxic if swalloed
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
N-Bromosuccinimide Price
- Product number
- N24609
- Product name
- Nitrosobenzene
- Purity
- ≥97%
- Packaging
- 10g
- Price
- $136
- Updated
- 2024/03/01
- Product number
- N24609
- Product name
- Nitrosobenzene
- Purity
- ≥97%
- Packaging
- 25g
- Price
- $263
- Updated
- 2024/03/01
- Product number
- N0367
- Product name
- Nitrosobenzene
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $78
- Updated
- 2024/03/01
- Product number
- N0367
- Product name
- Nitrosobenzene
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $213
- Updated
- 2024/03/01
- Product number
- 21009
- Product name
- Nitrosobenzene
- Purity
- ≥95%
- Packaging
- 1g
- Price
- $32
- Updated
- 2024/03/01
Nitrosobenzene Chemical Properties,Usage,Production
Chemical Properties
light yellow solid
Uses
Spin trap reagent. Has been used in the study of oxidative DNA damage and nitroso-compound-induced respiratory burst in neutrophils3,4.
Uses
Spin trap. Undergoes various addition, reduction, and oxidation reactions.
Definition
ChEBI: A nitroso compound that is the nitroso derivative of benzene; a diamagnetic hybrid of singlet O2 and azobenzene.
Purification Methods
Steam distil nitrosobenzene, then crystallise it from a small volume of EtOH with cooling below 0o, dry it over CaCl2 in a dessicator at atmospheric pressure, and store it under N2 at 0o. Alternatively it can be distilled onto a cold finger cooled with brine at ~-10o in a vacuum at 17mm (water pump), while heating in a water bath at 65-70o [Robertson & Vaughan J Chem Educ 27 605 1950]. [Beilstein 5 IV 702.]